SiO2纳米颗粒对二元硝酸盐表面张力的影响

张慧1, 李锐1, 熊亚选1*, 冷光辉2, 吴玉庭3, 徐鹏1, 马重芳3

化工新型材料 ›› 2021, Vol. 49 ›› Issue (1) : 157 -161.

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化工新型材料 ›› 2021, Vol. 49 ›› Issue (1) : 157-161. DOI: 10.19817/j.cnki.issn 1006-3536.2021.01.035
科学研究

SiO2纳米颗粒对二元硝酸盐表面张力的影响

    张慧1, 李锐1, 熊亚选1*, 冷光辉2, 吴玉庭3, 徐鹏1, 马重芳3
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Influence of SiO2 nanoparticle on surface tension of binary nitrate salt

  • Zhang Hui1, Li Rui1, Xiong Yaxuan1, Leng Guanghui2, Wu Yuting3, Xu Peng1, Ma Chongfang3
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摘要

表面张力直接影响着熔盐传热的液相传输系数,而在熔盐中加入纳米颗粒能够调节其表面张力。利用高温熔融法,将不同比例的SiO2纳米颗粒分散到二元硝酸熔盐中,制备了5种纳米熔盐。借助拉筒法对基盐和5种纳米熔盐在不同温度下的表面张力进行了实验研究,拟合得到基盐和5种纳米熔盐表面张力随温度变化的实验关联式,并对纳米熔盐的微观结构进行了分析。结果表明:在基盐中加入纳米颗粒会提高熔盐的表面张力,并且5种纳米熔盐的表面张力均随温度的升高而降低。

Abstract

Surface tension of molten salt directly affects the liquid phase transport coefficient,while nanoparticles can regulate the surface tension of molten salts.SiO2 nanoparticles with different concentrations were dispersed into a binary nitrate salt by high-temperature melting method,and five molten salt nanofluids were prepared.Then surface tension of the base salt and the five molten salt nanofluids was then measured by the pulling-escape method,and the correlations were fitted between the surface tension and the salt temperature.In addition,the micromorphology of the nanofluids was analyzed by scanning electron microscope method.Results shown that the SiO2 nanoparticles increased the surface tension of the nanofluids,and the surface tension decreased with the increase of salt temperature.

关键词

二元硝酸盐 / 纳米颗粒 / 表面张力 / 拉筒法

Key words

binary nitrate salt / nanoparticles / surface tension / pulling escape method

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SiO2纳米颗粒对二元硝酸盐表面张力的影响[J]. 化工新型材料, 2021, 49(1): 157-161 DOI:10.19817/j.cnki.issn 1006-3536.2021.01.035

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基金资助

国家自然科学基金(51206004)

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